Publication List

2016

(74) J.R. Swierk, K.P. Regan, J. Jiang, G.W. Brudvig, and C.A. Schmuttenmaer, Rutile TiO2 as an Anode Material for Water-Splitting Dye-Sensitized Photoelectrochemical Cells, ACS Energy Lett., accepted.

(73) N.S. McCool, J.R. Swierk, C.T. Nemes, C.A. Schmuttenmaer, T.E. Mallouk, Dynamics of Electron Injection in SnO2-TiO2 Core-Shell Electrodes for Water-splitting Dye-sensitized Photoelectrochemical Cells, J. Phys. Chem. Lett., 7, 2016, 2930-2934

(72) J. Jiang, J.R. Swierk, S. Hëdstrom, A.J. Matula, R.H. Crabtree, V.S. Batista, C.A. Schmuttenmaer, G.W. Brudvig, Molecular Design of Light-Harvesting Photosensitizers: Effect of Varied Linker Conjugation on Interfacial Electron Transfer, Phys. Chem. Chem. Phys., 2016, 18, 18678-18682

(71) K.P. Regan, C. Koenigsmann, S.W. Sheehan, S.J. Konezny, and C.A. Schmuttenmaer, Ultrafast Charge Carrier Dynamics of WO3 for Photoelectrochemical Cells, J. Phys. Chem. C2016, 120 (27), pp 14926–14933

(70) N.S. McCool, J.R. Swierk, C.T. Nemes, C.A. Schmuttenmaer, and T. E. Mallouk, Proton-Induced Trap States, Injection and Recombination Dynamics in Water-Splitting Dye-Sensitized Photoelectrochemical Cells, ACS Appl. Mater. Interfaces, in press. 

(69) D.J. Aschaffenburg, M.R.C. Williams, and C.A. Schuttenmaer, Terahertz spectroscopic polarimetry of generalized anisotropic media composed of Archimedean spiral arrays: Experiments and simulations, J. Chem. Phys., 2016, 144, 174705

(68) C. Li, C. Koenigsmann, F. Deng, A. Hagstrom, C.A. Schmuttenmaer, and J. Kim, Photocurrent Enhancement from Solid-State Triplet-Triplet Annihilation of Low-Intensity, Low-Energy Photons, ACS Photonics, in press. 

(67) J.R. Swierk, N.S. McCool, C.T. Nemes, T.E. Mallouk, and C.A. Schmuttenmaer,  Ultrafast Electron Injection Dynamics of Photoanodes for Water-Splitting Dye-Sensitized Photoelectrochemical CellsJ. Phys. Chem. C2016120 (11), 5940–5948

(66) S.F. Liew, S.M. Popoff, S.W. Sheehan, A. Goetschy, C.A. Schmuttenmaer, A.D. Stone, and H. Cao, Coherent Control of Photocurrent in a Strongly Scattering Photoelectrochemical SystemACS Photonics20163 (3), 449–455


2015

(65) C.T. Nemes, C. Koenigsmann, and C.A. Schmuttenmaer, Functioning Photoelectrochemical Devices Studied with Time-Resolved Terahertz Spectroscopy, J. Phys. Chem. Lett.20156 (16), 3257–3262
 

(64) W. Ding, M. Koepf, C. Koenigsmann, A. Batra, L. Venkataraman, C.F.A. Negre, G.W. Brudvig, R.H. Crabtree, C.A. Schmuttenmaer, and V.S. Batista, Computational Design of Intrinsic Molecular Rectifiers Based on Asymmetric Functionalization of N-PhenylbenzamideJ. Chem. Theory Comput.201511(12), 5888–5896

(63) R.L. Milot, and C.A. Schmuttenmaer, Electron Injection Dynamics in High-Potential Porphyrin Photoanodes, Acc. Chem. Res.201548(5), 1423–1431

(62) P.K. Poddutoori, J.M. Thomsen, R.L. Milot, S.W. Sheehan, C.F. Negre, V.K.R. Garapati, C.A. Schmuttenmaer, V.S. Batista, G.W. Brudvig, and A. van der Est, Interfacial Electron Transfer in High-Potential Photoanodes based on Phosphorus(V) Porphyrin Sensitizers Co-deposited on SnO2 with the IrIIICp* Water Oxidation PrecatalystJ. Mater. Chem. A, 20153, 3868-3879

(61) C. Li, C. Koenigsmann, W. Ding, B. Rudshteyn, K.R. Yang, K.P. Regan, S.J. Konezny, V.S. Batista, G.W. Brudvig, C.A. Schmuttenmaer, and J. Kim, Facet-Dependent Photoelectrochemical Performance of TiO2 Nanostructures: An Experimental and Computational Study, J. Am. Chem. Soc.2015137 (4), 1520–1529

(60) S.W. Sheehan, J.M. Thomsen, U. Hintermair, R H. Crabtree, G.W. Brudvig, and C.A. Schmuttenmaer, A molecular catalyst for ​water oxidation that binds to metal oxide surfaces, Nat. Commun., 2015, 6, 6469


2014

(59) C. Koenigsmann, T.S. Ripolles, B.J. Brennan, C.F.A. Negre, M. Koepf, A.C. Durrell, R.L. Milot, J.A. Torre, R.H. Crabtree, V.S. Batista, G.W. Brudvig, J. Bisquert, and C.A. Schmuttenmaer, Substitution of a hydroxamic acid anchor into the MK-2 dye for enhanced photovoltaic performance and water stability in a DSSCPhys. Chem. Chem. Phys.2014, 16(31),16629-41.

(58) J.B. Baxter, C. Richter, and C.A. Schmuttenmaer, Ultrafast Carrier Dynamics in Nanostructures for Solar Fuels, Annu. Rev. Phys. Chem.201465, 423-447

(57) W. Ding, C.F.A. Negre, J.L. Palma, A.C. Durrell, L.J. Allen, K.J. Young, R.L. Milot, C.A. Schmuttenmaer, G.W. Brudvig, R.H. Crabtree, and V.S. Batista, Linker Rectifiers for Covalent Attachment of Transition-Metal Catalysts to Metal-Oxide Surfaces, Chem. Phys. Chem.201415(6), 1138–1147


2013

(56) C.F.A Negre, R.L. Milot, L.A. Martini, W. Ding, R.H. Crabtree, C.A. Schmuttenmaer, and V.S. Batista, Efficiency of Interfacial Electron Transfer from Zn-Porphyrin Dyes into TiO2 Correlated to the Linker Single Molecule Conductance, J. Phys. Chem. C2013117(46), 24462-24470

(55) R.L. Milot, G.F. Moore, R.H. Crabtree, G.W. Brudvig, and C.A. Schmuttenmaer, Electron Injection Dynamics from Photoexcited Porphyrin Dyes into SnO2 and TiO2 NanoparticlesJ. Phys. Chem. C2013117(42), 42, 21662 - 21670

(54) M.R.C. Williams, D.J. Aschaffenburg, B.K. Ofori-Okai, and C.A. Schmuttenmaer, Intermolecular Vibrations in Hydrophobic Amino Acid Crystals: Experiments and Calculations, J. Phys. Chem. B2013117(36), 10444-10461

(53) L.A. Martini, G.F. Moore, R.L. Milot, L.Z. Cai, S.W. Sheehan, C.A. Schmuttenmaer, G.W. Brudvig, and R.H. Crabtree, Modular Assembly of High-Potential Zinc Porphyrin Photosensitizers Attached to TiO2 with a Series of Anchoring Groups, J. Phys. Chem. C, 2013117(28), 14526–14533

(52) T.P. Brewster, S.J. Konezny, S.W. Sheehan, L.A. Martini, C.A. Schmuttenmaer, V.S. Batista, and R.H. Crabtree, Hydroxamate Anchors for Improved Photoconversion in Dye-Sensitized Solar Cells, Inorg. Chem.201352(11), 6752-6764 

(51) S.W. Sheehan, H. Noh, G.W. Brudvig, H. Cao, and C.A. Schmuttenmaer, Plasmonic Enhancement of Dye-Sensitized Solar Cells Using Core-Shell-Shell Nanostructures, J. Phys. Chem. C, 2013, 117(2), 927-934


2012

(50) D.J. Aschaffenburg, M.R.C. Williams, D. Talbayev, D.F. Santavicca, D.E. Prober, and C.A. Schmuttenmaer, Efficient measurement of broadband terahertz optical activityAppl. Phys. Lett., 2012100, 241114

(49) K.J. Young, L.A. Martini, R.L. Milot, I.I.I. Snoeberger, C. Robert, V.S. Batista, C.A. Schmuttenmaer, R.H. Crabtree, and G.W. Brudvig, Light-driven water oxidation for solar fuelsCoord. Chem. Rev.2012256, 2503-2520

(48) G.F. Moore, S.J. Konezny, H.E. Song, R.L. Milot, J.D. Blakemore, M.L. Lee, V.S. Batista, C.A. Schmuttenmaer, R.H. Crabtree, and G.W. Brudvig, Bioinspired High-Potential Porphyrin PhotoanodesJ. Phys. Chem. C2012116 (7), 4892–4902


2011

(47) S.J. Konezny, C. Richter, R.C. Snoeberger, A.R. Parent, G.W. Brudvig, C.A. Schmuttenmaer, and V.S. Batista, Fluctuation-Induced Tunneling Conductivity in Nanoporous TiO2 Thin Films, J. Phys. Chem. Lett.20112(15), 1931-1936

(46) G.F. Moore, J.D. Blakemore, R.L. Milot, J.F. Hull, H.E. Song, L.Z. Cai, C.A. Schmuttenmaer, R.H. Crabtree, and G.W. Brudvig, A visible light water-splitting cell with a photoanode formed by codeposition of a high-potential porphyrin and an iridium water-oxidation catalystEnergy Environ. Sci.20114, 2389-2392

(45) D.E. Rosenfeld, and C.A. Schmuttenmaer, Dynamics of the Water Hydrogen Bond Network at Ionic, Nonionic, and Hydrophobic Interfaces in Nanopores and Reverse Micelles, J. Phys. Chem. B2011115(5), 1021-1031

(44) M.R.C Williams, A.B. True, A.F. Izmaylov, T.A. French, K. Schroeck, and C.A. Schmuttenmaer, Terahertz Spectroscopy of Enantiopure and Racemic Polycrystalline ValinePhys. Chem. Chem. Phys.201113, 11719-11730

(43) A.B. True, K. Schroeck, T.A. French, and C.A. Schmuttenmaer, Terahertz Spectroscopy of Histidine Enantiomers and Polymorphs, J. Infrared Millim. Terahertz Waves201132, 691-698


2010

(42) C. Richter, and C.A. Schmuttenmaer, Exciton-like trap states limit electron mobility in TiO2 nanotubesNat. Nanotechnol.20105, 769-772

(41) S.M. Harrel, R.L. Milot, J.M. Schleicher, and C.A. Schmuttenmaer, Influence of free-carrier absorption on terahertz generation from ZnTe(110)J. Appl. Phys.2010107, 033526


2009

(40) J.B. Baxter, and C.A. Schmuttenmaer, Carrier dynamics in bulk ZnO. II. Transient photoconductivity measured by time-resolved terahertz spectroscopyPhys. Rev. B200980, 235206

(39) J.M. Schleicher, S.M. Harrel, and C.A. Schmuttenmaer, Effect of spin-polarized electrons on terahertz emission from photoexcited GaAsJ. Appl. Phys.2009105, 113116

(38) W.R. McNamara, R.C. Snoeberger, G.H. Li, C. Richter, L.J. Allen, R.L. Milot, C.A. Schmuttenmaer, R.H. Crabtree, G.W. Brudvig, and V.S. Batista, Hydroxamate anchors for water-stable attachment to TiO2 nanoparticlesEnergy Environ. Sci.20092, 1173-1175

(37) G.H. Li, C.P. Richter, R.L. Milot, L.Z. Cai, C.A. Schmuttenmaer, R.H. Crabtree, G.W. Brudvig, and V.S. Batista, Synergistic effect between anatase and rutile TiO2 nanoparticles in dye-sensitized solar cellsDalton Trans.2009, 10078-10085


2008

(36) W.R. McNamara, R.C. Snoeberger, G.H. Li, J.M. Schleicher, C.W. Cady, M. Poyatos, C.A. Schmuttenmaer, R.H. Crabtree, G.W. Brudvig, and V.S. Batista, Acetylacetonate Anchors for Robust Functionalization of TiO2 Nanoparticles with Mn(II)-Terpyridine Complexes, J. Am. Chem. Soc.2008130(43), 14329-14338

(35) N. Iguchi, C.W. Cady, R.C. Snoeberger, B.M. Hunter, E.M. Sproviero, C.A. Schmuttenmaer, R.H. Crabtree, G.W. Brudvig, and V.S. Batista, Characterization of Siloxane Adsorbates Covalently Attached to TiO2, Physical Chemistry of Interfaces and Nanomaterials Vii20087034, C340-C340

(34) Mandal, K. C., S. H. Kang, M. Choi, J. Chen, X. C. Zhang, J. M. Schleicher, C. A. Schmuttenmaer, and N. C. Fernelilis, III-VI chalcogenide semiconductor crystals for broadband tunable THz sources and sensorsIEEE J. Sel. Top. Quantum Electron.200814, 284-288


2007

(33) J.B Baxter, and C.A. Schmuttenmaer, Carrier Dynamics in ZnO Nanowires and Films Measured by Time-Resolved THz Spectroscopy, Ultrafast Phenomena XV, 200788, 766-768

(32) M.O. Reese, D.F. Santavicca, D.E. Prober, A.B. True, and C.A. Schmuttenmaer, Niobium direct detectors for fast and sensitive terahertz spectroscopyRev. Sci. Instrum.200778, 086111

(31) S.G. Abuabara, C.W. Cady, J.B. Baxter, C.A. Schmuttenmaer, R.H. Crabtree, G.W. Brudvig, and V.S. Batista, Ultrafast photooxidation of Mn(II)-Terpyridine complexes covalently attached to TiO2 nanoparticlesJ. Phys. Chem. C2007111(32), 11982-11990

(30) D.F. Santavicca, M.O. Reese, A.B. True, C.A. Schmuttenmaer, and D.E. Prober, Antenna-coupled niobium bolometers for terahertz spectroscopyIEEE Trans. Appl. Supercond.200717, 412-415

(29) J.M. Schleicher, S.M. Harrel, C.A. Schmuttenmaer, E. Beaurepaire, and J. Y. Bigot, Characterization of magnetization dynamics using terahertz emission spectroscopy, Ultrafast Phenomena XV, 200788, 793-795


2006

(28) J.B Baxter, and C.A. Schmuttenmaer, Conductivity of ZnO nanowires, nanoparticles, and thin films using time-resolved terahertz spectroscopyJ. Phys. Chem. B2006110(50), 25229-25239

(27) D.E. Rosenfeld, and C. A. Schmuttenmaer, Dynamics of water confined within reverse micellesJ. Phys. Chem. B2006110, 14304-1431


2004

(26) E. Beaurepaire, G.M. Turner, S.M. Harrel, M.C. Beard, J.Y. Bigot, and C.A. Schmuttenmaer, Coherent terahertz emission from ferromagnetic films excited by femtosecond laser pulsesAppl. Phys. Lett.200484, 3465-3467

(25) C.A. Schmuttenmaer, Exploring dynamics in the far-infrared with terahertz spectroscopyChem. Rev.2004104, 1759-1779


2003

(24) M.C. Beard, G.M. Turner, J.E. Murphy, O.I. Micic, M.C. Hanna, A.J. Nozik, and C.A. Schmuttenmaer, Electronic coupling in InP nanoparticle arraysNano Lett.20033(12), 1695-1699

(23) C.A. Schmuttenmaer, M.C. Beard, and G.M. Turner, Exploring sub-picosecond dynamics in the far-infrared with THz spectroscopy, Ultrafast Phenomena Xiii, 200371, 407-411

(22) G.M. Turner, M.C. Beard, and C.A. Schmuttenmaer, Photoconductivity of dye-sensitized titanium dioxide films measured by time-resolved THz spectroscopy (TRTS), Ultrafast Phenomena Xiii, 200371, 331-333

(21) C.A. Schmuttenmaer, G.M. Turner, and M.C. Beard, Transient photoconductivity in CdSe nanoparticles and nanocrystalline TiO2 as measured by time-resolved terahertz spectroscopy, Physical Chemistry of Interfaces and Nanomaterials II, 20035223, 64-69


2002

(20) M.C. Beard, G.M. Turner, and C.A. Schmuttenmaer, Measuring intramolecular charge transfer via coherent generation of THz radiationJ. Phys. Chem. A2002106(6), 878-883

(19) M.C. Beard, G.M. Turner, and C.A. Schmuttenmaer, Progress towards two-dimensional biomedical imaging with THz spectroscopyPhys. Med. Biol.200247, 3841-3846

(18) M.C. Beard, G.M. Turner, and C.A. Schmuttenmaer, Size-dependent photoconductivity in CdSe nanoparticles as measured by time-resolved terahertz spectroscopyNano Lett.20022, 983-987

(17) M.C. Beard, G.M. Turner, and C.A. Schmuttenmaer, Terahertz spectroscopyJ. Phys. Chem. B2002106(29), 7146-7159

(16) G.M. Turner, M.C. Beard, and C.A. Schmuttenmaer, Carrier localization and cooling in dye-sensitized nanocrystalline titanium dioxide, J. Phys. Chem. B2002106(45), 11716-11719

(15) M.C. Beard, G.M. Turner, and C.A. Schmuttenmaer, Low frequency, collective solvent dynamics probed with time-resolved THz spectroscopy, ACS SYM SER2002820, 44-57


2001

(14) J.P. Wolf, Y.L. Pan, G.M. Turner, M.C. Beard, C.A. Schmuttenmaer, S. Holler, and R.K. Chang, Ballistic trajectories of optical wave packets within microcavitiesPhys. Rev. A200164, 023808

(13) D.S. Venables, K. Huang, and C.A. Schmuttenmaer, Effect of reverse micelle size on the librational band of confined water and methanol, J. Phys. Chem. B2001105(38), 9132-9138

(12) M.C. Beard, G.M. Turner, and C.A. Schmuttenmaer, Subpicosecond carrier dynamics in low-temperature grown GaAs as measured by time-resolved terahertz spectroscopyJ. Appl. Phys.200190, 5915-5923

(11) M.C. Beard, and C.A. Schmuttenmaer, Using the finite-difference time-domain pulse propagation method to simulate time-resolved THz experimentsJ. Chem. Phys.2001114, 2903-290


2000

(10) C.A. Schmuttenmaer, and D.S. Venables, Spectroscopy and dynamics of mixtures of water with acetone, acetonitrile, and methanolJ. Chem. Phys.2000113, 24, 11222-11236

(9) D.S. Venables, and C.A. Schmuttenmaer, Structure and dynamics of nonaqueous mixtures of dipolar liquids. II. Molecular dynamics simulationsJ. Chem. Phys.2000113, 3249-3260

(8) D.S. Venables, A. Chiu, and C.A. Schmuttenmaer, Structure and dynamics of nonaqueous mixtures of dipolar liquids. I. Infrared and far-infrared spectroscopyJ. Chem. Phys.2000113, 3243-3248

(7) G.M. Turner, M.C. Beard, D.S. Venables, and C.A. Schmuttenmaer, A direct measurement of intermolecular solvation dynamics using time-resolved THz spectroscopy (TRTS), Photoinduced Charge Transfer2000, 223-232

(6) M.C. Beard, G.M. Turner, and C.A. Schmuttenmaer, Measurement of electromagnetic radiation emitted during rapid intramolecular electron transferJ. Am. Chem. Soc.2000122, 11541-11542

(5) M.C. Beard, G.M. Turner, and C.A. Schmuttenmaer, Transient photoconductivity in GaAs as measured by time-resolved terahertz spectroscopyPhys. Rev. B200062, 15764-15777


1999

(4) J.T. Kindt, and C.A. Schmuttenmaer, Theory for determination of the low-frequency time-dependent response function in liquids using time-resolved terahertz pulse spectroscopyJ. Chem. Phys.1999110, 8589-8596


1998

(3) D.S. Venables, and C. A. Schmuttenmaer, Far-infrared spectra and associated dynamics in acetonitrile-water mixtures measured with femtosecond THz pulse spectroscopyJ. Chem. Phys.1998108, 4935-4944


1997

(2) Kindt, J. T., and C. A. Schmuttenmaer, Far-infrared absorption spectra of water, ammonia, and chloroform calculated from instantaneous normal mode theory, J. Chem. Phys.1997106, 4389-4400


1996

(1) J.T. Kindt, and C.A. Schmuttenmaer, Far-infrared dielectric properties of polar liquids probed by femtosecond terahertz pulse spectroscopyJ. Phys. Chem.1996100, 10373-10379